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Gas Purification in the Manufacture of PET and PTA

Inert gases are used in the thermal post-treatment of polymer raw materials, for instance in the SSP process (Solid State Polycondensation) for polyester materials. The impurities, which are enriched in the inert gas, are organic compounds, such as aldehydes, glycols and oligomers. These impurities are removed from the inert gas in circulation by means of catalytic oxidation.
Heraeus-catalysts can be used in this process with a minimum (stoichiometric) excess of oxygen. The purified gas can be fed back into the circulation immediately after a subsequent drying step.
Heraeus-catalysts are not only used in the purification of inert gas in the SSP reactor, but also in the purification of exhaust gases in PTA equipment.

Parameter for catalytical oxidation
PET-Process (Examples)
Typical Process Parameter
Flow 2,.000 – 15.000 Nm³/h
Pollutants (extract):
Acetaldehyde 10 – 500 ppmv
Ethylene glycol 500 – 3.000 ppmv
Water 0,5 – 1,0 Vol.-%

Plastic bottles
Survey Catalysts
Catalysts Metal(s)
K-02120 Pt/Pd
K-02130 Pt/Pd
K-02131 Pt/Pd
K-02134 Pt/Pd
K-080x Cu/Mn

Recommended Conditions
Space velocity 4.000 – 8.000 1/h
Inlet temperature 280 – 350 °C
Oxygen excess 5 – 20 vppm
Conversion expected > 99.5 %